Effect of Anode Material on Electrochemical Oxidation of Alcohols

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Effect of Anode Material on Electrochemical Oxidation of Alcohols ( effect-anode-material-electrochemical-oxidation-alcohols )

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Molecules 2021, 26, 2144 30 of 37 References Informed Consent Statement: Not applicable. Data Availability Statement: Data is contained within the article. Conflicts of Interest: The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, or in the decision to publish the results. Abbreviations List of used symbols CNC Carbon nanocages CNT Carbon nanotubes COads Adsorbed carbon oxide intermediates DAFC Direct alcohol fuel cell DMFC Direct methanol fuel cell ECSA Electrochemically active surface EGr Exfoliated graphite EG Ethylene glycol EGOR Ethylene glycol oxidation reaction ESA Electrode surface area EOR Ethanol oxidation reaction GC Glassy carbon GNS Graphene nanosheets MOR Methanol oxidation reaction MWCNT Multi-walled carbon nanotubes OHads Adsorbed hydroxide ions OCP open-circuit potential PEM Proton-exchange membrane PEMFC Proton-exchange membrane fuel cell rGO Reduced graphene oxide RHE Reversible hydrogen electrode SEM Scanning electron microscope TEM Transmission electron microscope 1. Çelebi, Y.; Aydın, H. An overview on the light alcohol fuels in diesel engines. Fuel 2019, 236, 890–911. [CrossRef] 2. Ott, J.; Gronemann, V.; Pontzen, F.; Fiedler, E.; Grossmann, G.; Kersebohm, D.B.; Weiss, G.; Witte, C. Methanol. In Ullmann’s Encyclopedia of Industrial Chemistry; Wiley-VCH Verlag GmbH & Co. KgaA: Weinheim, Germany, 2012; ISBN 9783527303854. 3. Verhelst, S.; Turner, J.W.; Sileghem, L.; Vancoillie, J. Methanol as a fuel for internal combustion engines. Prog. Energy Combust. Sci. 2019, 70, 43–88. [CrossRef] 4. Sheldon, D. Methanol production-A technical history. Johnson Matthey Technol. Rev. 2017, 61, 172–182. [CrossRef] 5. Zhu, J.Y.; Yoon, S.H.; Liu, P.H.; Chai, X.S. Methanol formation during alkaline wood pulping. TAPPI J. 2000, 83, 65. 6. Sequeira, C.A.C.; Cardoso, D.S.P.; Martins, M.; Amaral, L. Novel materials for fuel cells operating on liquid fuels. AIMS Energy 2017, 5, 458–481. [CrossRef] 7. Lamy, C.; Belgsir, E.M.; Léger, J.M. Electrocatalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC). J. Appl. Electrochem. 2001, 31, 799–809. [CrossRef] 8. Leo, T.J.; Raso, M.A.; Navarro, E.; Sánchez-De-La-Blanca, E. Comparative exergy analysis of direct alcohol fuel cells using fuel mixtures. J. Power Sources 2011, 196, 1178–1183. [CrossRef] 9. Zhao, T.S.; Yang, W.W. Fuel Cells-Direct Alcohol Fuel Cells | Modeling. Encycl. Electrochem. Power Sources 2009, 436–445. [CrossRef] 10. Mandikarappa Subramani, S.; Gantigiah, K. Deposition of cobalt nanoparticles on reduced graphene oxide and the electrocatalytic activity for methanol and ethanol oxidation. Mater. Res. Express 2019, 6. [CrossRef] 11. Zhu, C.; Guo, S.; Dong, S. PdM (M = Pt, Au) bimetallic alloy nanowires with enhanced electrocatalytic activity for electro-oxidation of small molecules. Adv. Mater. 2012, 24, 2326–2331. [CrossRef] 12. Zhang, M.; Yan, Z.; Xie, J. Core/shell Ni@Pd nanoparticles supported on MWCNTs at improved electrocatalytic performance for alcohol oxidation in alkaline media. Electrochim. Acta 2012, 77, 237–243. [CrossRef] 13. Bai, J.; Liu, D.; Yang, J.; Chen, Y. Nanocatalysts for Electrocatalytic Oxidation of Ethanol. ChemSusChem 2019, 12, 2117–2132. [CrossRef] 14. Radenahmad, N.; Afif, A.; Petra, P.I.; Rahman, S.M.H.; Eriksson, S.G.; Azad, A.K. Proton-conducting electrolytes for direct methanol and direct urea fuel cells-A state-of-the-art review. Renew. Sustain. Energy Rev. 2016, 57, 1347–1358. [CrossRef]

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