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Chapter 3. Sustainable Hydrocarbon Fuels by Recycling CO2 with Renewable/Nuclear Energy 49 Table 3-1. History of work done on the full synthetic fuel cycle concept, using the codes of Figure 3-3 to map the pathways. Arrows indicate that the process was integrated into the prior stage. Italics indicate that a process was only briefly mentioned. Years 1970s 1980s Reference(s) [4] [5] [7] [7] [9] [10, 11] [14] Energy collection CO2 collection Dissociation GL DN N7 Fuel synthesis G(K+L) (C/D)(N/P)(R+Y) G(K+L) ER SWY 27 SWY 267 GL DN(R+Y) 267 G... DPR G(K+L) DOR G(K+L) minerals-PR RVZ (Z+S)...7 ...Y (1/2)7 SWY 267 1990s [16] [17] [15] ...L DOR (R+S)W(Y+Z+1) ...L DN(R+Y) SWY G(K+L) ER SVY 27 27 27 27 57 17 457 27 / 57 (2/3)(5/6)7 57 2000s to today [18, 19] [19] [20] [22, 23] [27-29] [25, 26] [34] [12] F(K+L) F(K+L) FL F(K+L) ...L (H+I)L ...L D(O/P)R SWY DPR (R+S)V5 ER SWY ER RTZ DPR (R+S)W5 / SWY ER SWY BN(R+Y) (R+S)V5 G(K+L) CN(R+Y) S(W/V)Y 267 [24] FK (R/S)U(Y/Z/5) 57a [35] [36] [30-33, 37-39] G(K+L) biomass (R+S)V5 57 (F/H)L ER (R+S)V5 57 (F/H/I/J)L BPR / A...R (R+S)V5 57 aThe cited reference does not include fuel synthesis but based on the name of their research program and interviews, the authors have the intention to produce liquid hydrocarbon fuels. Zeman and Keith [40] recently reviewed various means of attaining carbon-neutral hydrocarbons, including producing hydrocarbons from a CO2 feedstock. To produce fuels from CO2, they advocate using fossil resources. In their proposed CO2 recycling process, hydrogen is produced from fossil resources in a carbon-neutral manner by capturing and sequestering the CO2 emissions during the conversion, CO2 is captured from the atmosphere, and hydrocarbons are synthesized from the H2 and air-captured CO2. Although such a process is feasible, it usually does not make sense to use fossil energy in a CO2 recycling process. The fossil resource already contains carbon in an energetic state. Using this fossil carbon to drive a CO2 recycling scheme results in generation of more CO2 which must then be sequestered. The same end result could be achieved by sequestering the captured CO2 in the first place rather than recycling it. Indeed, their proposed CO2 recycling pathway is actually an alternate version of the pathway shown in Figure 3-2c—producing a fossil-based hydrocarbon and then using off-site air-capture of CO2 with sequestration to offset emissions from consumption of the fuel—which they also consider. It is more limited and most likely more expensive than the Figure 3-2c pathway in that the airPDF Image | Electrolysis of CO2 and H2O
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