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Chapter 6. Molybdate Based Ceramic Electrode Materials 188 SVM [70, 71] and the similar CaV0.5Mo0.5O3, [71, 82], as well as STM [69]. These materials are much more stable than SM at higher pO2, retaining high conductivity at pO2 as high as 10-17 atm, which corresponds to H2O-rich electrolysis type conditions with a pH2O/pH2 ratio of 9 (Figure 6-6c and Figure 6-6f). It appears that conductivity was gained from SrMoO3 and some stability gained from SrTiO3 and SrVO3. Whereas SrTiO3 is an insulator, SrVO3 has been reported to have high metallic electronic conductivity [83, 84]. Figure 6-6. Electrical conductivity versus temperature or pO2 for (a) SM, (b,c) SVM, (d) LM, and (e,f) STM. In the pO2 graphs (c,f), one point was measured every 3 minutes and the shading of the points changes from black to light gray with time. The amorphous lanthanum molybdate LM, on the other hand, exhibited low conductivity with semiconductor behavior – around 0.6 S/cm at 800 °C in 10-20 atm O2 and slightly lower at 0.5 S/cm with higher pO2 (Figure 6-6d). The log conductivity was linear with 1/T (not shown). The conductivity had not been reported in the LM anode study [24]. This low conductivity is only sufficient for a thin active layer of an electrode, not a current collecting layer [2, 85]. The conductivity measurements for the air-sintered double perovskite sample SMM_1 are shown in Figure 6-7. At 800 °C in the very reducing dry 9% H2/Ar atmosphere (pO2=10-24 atm), it took more than 600 hours to fully reduce the material. The final value was about 3.5 S/cm. On the other hand, the reducing-sintered sample SMM_2 did not need further reduction and reached a higher conductivity of 8.1 S/cm at 800 °C in 10-20 atm O2 (Figure 6-8). ThePDF Image | Electrolysis of CO2 and H2O
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