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are re-equilibrated to CO2 gas as shown in equation 3. This method has been the basis for standard quantitative ocean [CO2]T measurements for over 25 years [12]. H2O H2O [CO2(g)]air ⇄ [CO2(aq)] ⇄ [H2CO3(aq)] (1) H2O H2O CO2(g) ⇄ CO2(aq) ⇄ H2CO3(aq) ⇄ 2HCO3-(aq) ⇄ CO32-(aq) + H2O(l) + CO2(g) (2) HCO3- + H+ ⇄ H2CO3 ⇄ H2O + CO2 (g) (3) NRL transitioned the technology from the laboratory to a marine environment for the purpose of scaling-up and integrating processes. In this environment at the larger scale the E-CEM was evaluated continuously under different operating conditions that led to improvements in process efficiencies and module design. As a result NRL along with commercial partners has successfully designed and developed an E-CEM prototype that is capable of producing more than enough feedstock (CO2 and H2) to produce a gallon per day of liquid hydrocarbon. This fifty time scale-up in E-CEM seawater processing along with changes in electrode water composition that will be used for the new prototype have led to this test series. These test are directed at assessing E-CEM performance as a function of different water composition and understanding and controlling E-CEM effluent discharge water composition with respect to pH and chlorine content. These data will be used to ensure E-CEM prototype system performance and discharge compliance. 2.0 OBJECTIVE The objective of these evaluations is to determine the effects of using different water compositions fed to the electrode compartments of the E-CEM. A reverse osmosis (RO) system is currently used to supply the electrodes with water. The following key technical challenges associated with changing the RO water supply to Key West-city water on the E-CEM performance are addressed in this test series: E-CEM effluent discharge pH Anode effluent chlorine content Cathode effluent pH E-CEM process electrical efficiency 3.0 APPROACH In these test series an E-CEM carbon capture skid was operated at NRL’s Marine Corrosion Facility in Key West, Florida two separate occasions (February and April of 2017) to evaluate the performance of the E-CEM using KW city water as the electrode influent. 2PDF Image | Extraction CO2 H2 in Seawater Electrolytic Cation Exchange
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