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160.0 140.0 120.0 100.0 80.0 60.0 40.0 20.0 0.0 0 5 10 15 20 Time (Minutes) Figure 10. Average free chlorine concentration as a function of KW-city electrode flowrate and UV source 60 gpd (●) no treatment (○)UV 750 mJ/cm2; 30 gpd (■) no treatment (□) 1,500 mJ/cm2; batch 30 gpd (▲) no treatment () 1,500 mJ/cm2 When the flowrate to the electrode compartments is reduced from 60 gpd (227 lpd) to 30 gpd (113.5 lpd) the average free chlorine measured over the polarity cycles increased by 39% (solid squares). A larger UV source at 1,500 mJ/cm2 was used to treat the anode effluent and as a result the free chlorine was reduced an average of 72% from 126 mg/L to 36 mg/L over the average of the two polarity cycles (open squares). At the same electrode flowrate of 30 gpd the total anode effluent was collected as a batch over a twenty minute cycle and the free chlorine was measured for the total anode batch solution. The average free chlorine for two cycles measured 132 mg/L (closed triangle). Similarly2the free chlorine was reduced by 62% to 50 mg/L after exposure to UV source at 1,500 mJ/cm (open triangle). These data support that UV treatment of the anode compartment will significantly reduce the chlorine content of the water. Near term evaluations will focus on the treatment of the effluent anode with UV and aerating to determine the effluent chlorine content of the recombined 19 mg/L Chlorine Anode CompartmentPDF Image | Extraction CO2 H2 in Seawater Electrolytic Cation Exchange
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