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Fuel Cell Handbook (Seventh Edition)

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Fuel Cell Handbook (Seventh Edition) ( fuel-cell-handbook-seventh-edition )

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Figure 4-5 Influence of Temperature on O2, (air) Reduction in 12 N KOH. Source: Fig. 10, p. 324, Reference (21). Early data by Clark, et al. (22) indicated a temperature coefficient for AFCs operating between 50 to 70 °C of about 3 mV/°C at 50 mA/cm2, and cells with higher polarization had higher temperature coefficients under load. Later measurements by McBreen, et al. (23) on H2/air single cells (289 cm2 active area, carbon-based Pd anode and Pt cathode) with 50 percent KOH showed that the temperature coefficient above 60 °C was considerably lower than that obtained at lower temperatures, as shown in Figure 4-6. The McBreen data suggest the following expressions for evaluating the change in voltage (∆VT) as a function of temperature (T) at 100 mA/cm2: or ∆Vt (mV) = 4.0 (T2-T1) for T < 63 °C (4-5) ∆Vt (mV) = 0.7 (T2-T1) for T > 63 °C (4-6) Alkaline cells exhibit reasonable performance when operating at low temperatures (room temperature up to about 70 °C). This is because the conductivity of KOH solutions is relatively high at low temperatures. For instance, an alkaline fuel cell designed to operate at 70 °C will reduce to only half power level when its operating temperature is reduced to room temperature (24). 4-10

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