Fuel Cell Handbook (Seventh Edition)

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Fuel Cell Handbook (Seventh Edition) ( fuel-cell-handbook-seventh-edition )

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ANODE = H2 + CO3 ANODE CATA YST CATHOD CATHODE HYDROGEN AND CO CONTAINING FUEL e e → H2O + CO2 + 2e CO+H2O→CO2 +H2 +Heat ANODE CATALYST ELECTROLYTE CATHODE CATHODE CATALYST - = 1 / 2 O2 + C O2 + 2 e → C O3 1⁄2O2 +CO2 +2e→CO3= CO2 + Air Figure 6-1 Principles of Operation of Molten Carbonate Fuel Cells (FuelCell Energy) Besides the reaction involving H2 and O2 to produce H2O, Equation 6-3 shows a transfer of CO2 from the cathode gas stream to the anode gas stream via the CO3= ion, with 1 mole CO2 transferred along with two Faradays of charge, or 2 gram moles of electrons. The reversible potential for an MCFC, taking into account the transfer of CO2, is given by the equation RTPP12 RTP E=E°+2Fln H2 O2 +2Fln CO2,c (6-4) PH2O PCO2,a where the subscripts a and c refer to the anode and cathode gas compartments, respectively. When the partial pressures of CO2 are identical at the anode and cathode, and the electrolyte is invariant, the cell potential depends only on the partial pressures of H2, O2, and H2O. Typically, the CO2 partial pressures are different in the two electrode compartments and the cell potential is affected accordingly. The need for CO2 at the cathode requires some schemes that will either 1) transfer the CO2 from the anode exit gas to the cathode inlet gas ("CO2 transfer device"), 2) produce CO2 by combusting the anode exhaust gas, which is mixed directly with the cathode inlet gas, or 3) supply CO2 from an 6-2 FCE39c 81401

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