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Table 6-1 Evolution of Cell Component Technology for Molten Carbonate Fuel Cells Component Ca. 1965 Ca. 1975 Current Status Anode • Pt, Pd, or Ni • Ni-10 Cr • Ni-Cr/Ni-Al/Ni-Al-Cr • 3-6 μm pore size • 45 to 70 percent initial porosity • 0.20 to .5 mm thickness • 0.1 to1 m2/g Cathode • Ag2O or lithiated NiO • lithiated NiO • lithiated NiO-MgO • 7 to15 μm pore size • 70 to 80 percent initial porosity • 60 to 65 percent after lithiation and oxidation • 0.5 to 1 mm thickness • 0.5 m2/g Electrolyte • MgO • mixture of α-, β-, • γ-LiAlO2, α-LiAlO2 • 0.1to12m2/g • 0.5 to1 mm thickness Support and γ-LiAlO2 • 10to20m2/g • 1.8 mm thickness Electrolytea (wt percent) • 52 Li-48 Na • 43.5 Li-31.5 Na-25 K • "paste" • 62 Li-38 K • hot press "tile" • 1.8 mm thickness • 62 Li-38 K • 60 Li-40 Na 51 Li-48 Na • tape cast • 0.5 to1 mm thickness a - Mole percent of alkali carbonate salt Specifications for the anode and cathode were obtained from References (6), (10), and (11). 6-5PDF Image | Fuel Cell Handbook (Seventh Edition)
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