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Fuel Cell Handbook (Seventh Edition)

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Fuel Cell Handbook (Seventh Edition) ( fuel-cell-handbook-seventh-edition )

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composition contains O2 and CO2 in the stoichiometric ratio that is needed in the electrochemical reaction at the cathode (Equation (6-2)). With this gas composition, little or no diffusion limitations occur in the cathode because the reactants are provided primarily by bulk flow. The other gas composition, which contains a substantial fraction of N2, yields a cathode performance that is limited dilution by an inert gas. Figure 6-4 Effect of Oxidant Gas Composition on MCFC Cathode Performance at 650°C, (Curve 1, 12.6 percent O2/18.4 percent CO2/69.0 percent N2; Curve 2, 33 percent O2/67 percent CO2) In the 1980s, the performance of MCFC stacks increased dramatically. During the 1990s, cells as large as 1.0 m2 are being tested in stacks. Most recently, the focus has been on achieving performance in a stack equivalent to single cell performance. Cells with an electrode area of 0.3 m2 were routinely tested at ambient and above ambient pressures with improved electrolyte structures made by tape-casting processes (22). Several stacks underwent endurance testing in the range of 7,000 to 10,000 hours. The voltage and power as a function of current density after 960 hours for a 1.0 m2 stack consisting of 19 cells are shown in Figure 6-5. The data were obtained with the cell stack at 650 °C and 1 atmosphere. 6-14

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