PDF Publication Title:
Text from PDF Page: 202
Accordingly, the good compatibility with YSZ and the high electro-catalytic activity make LSM the cathode material of choice of SOFCs operating around 1000 °C. For intermediate-temperature operation (700 to 800 °C), a composite layer (typically 20 to 40 μm thick) of YSZ and LSM is often used to overcome the modest ion conductivity at lower temperatures (18, 19, 20). Alternatively, LSCF or LSF are also pursued for such applications. A serious challenge in the use of LSM as a cathode material in intermediate temperature SOFC stems from the use of metallic interconnects. Many of these metals contain chromium, which forms a stable protective oxide (chromia) layer with reasonable conductivity (see Section 7.1.4 on interconnects for more details). However, chromia vapors can lead to serious poisoning of the cathode (21, 22). Although one might attribute this problem more to the interconnect material than to the cathode, the poisoning effect was found to depend strongly on the electrolyte/cathode material combination. Figure 7-3 Impact of Chromia Poisoning on the Performance of Cells with Different Electrolytes (From (21)) For low-temperature operation (below 700 °C), the use of LSM as the cathode material represents significant potential loss, and other materials are being pursued. 7.1.4 InterconnectMaterials Broadly, interconnect materials for SOFC fall into two categories: conductive ceramic (perovskite) materials for operation at high temperature (900 to 1000 °C) and metallic alloys for lower temperature operation. Though the shape of SOFC interconnects depends heavily on the cell and stack design, the materials choice is almost entirely determined by physical and chemical stability under operating conditions. The ceramic interconnects used in higher temperature SOFCs are primarily doped lanthanum and yttrium chromites (dopants typically include Mg, Sr, Ca, Ca/Co). These perovskites are unique in that they exhibit high electronic conductivity and resist reduction under exposure to syngas at high temperatures. Electronic conductivity of these materials increases with temperature (making them unsuitable for use at low temperatures). At 1,000 °C the conductivities of these materials 7-6PDF Image | Fuel Cell Handbook (Seventh Edition)
PDF Search Title:
Fuel Cell Handbook (Seventh Edition)Original File Name Searched:
fuel-cell-handbook.pdfDIY PDF Search: Google It | Yahoo | Bing
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
IT XR Project Redstone NFT Available for Sale: NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Be part of the future with this NFT. Can be bought and sold but only one design NFT exists. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Turbine IT XR Project Redstone Design: NFT for sale... NFT for high tech turbine design with one part 3D printed counter-rotating energy turbine. Includes all rights to this turbine design, including license for Fluid Handling Block I and II for the turbine assembly and housing. The NFT includes the blueprints (cad/cam), revenue streams, and all future development of the IT XR Project Redstone... More Info
Infinity Turbine ROT Radial Outflow Turbine 24 Design and Worldwide Rights: NFT for sale... NFT for the ROT 24 energy turbine. Be part of the future with this NFT. This design can be bought and sold but only one design NFT exists. You may manufacture the unit, or get the revenues from its sale from Infinity Turbine. Royalties go to the developer (Infinity) to keep enhancing design and applications... More Info
Infinity Supercritical CO2 10 Liter Extractor Design and Worldwide Rights: The Infinity Supercritical 10L CO2 extractor is for botanical oil extraction, which is rich in terpenes and can produce shelf ready full spectrum oil. With over 5 years of development, this industry leader mature extractor machine has been sold since 2015 and is part of many profitable businesses. The process can also be used for electrowinning, e-waste recycling, and lithium battery recycling, gold mining electronic wastes, precious metals. CO2 can also be used in a reverse fuel cell with nafion to make a gas-to-liquids fuel, such as methanol, ethanol and butanol or ethylene. Supercritical CO2 has also been used for treating nafion to make it more effective catalyst. This NFT is for the purchase of worldwide rights which includes the design. More Info
NFT (Non Fungible Token): Buy our tech, design, development or system NFT and become part of our tech NFT network... More Info
Infinity Turbine Products: Special for this month, any plans are $10,000 for complete Cad/Cam blueprints. License is for one build. Try before you buy a production license. May pay by Bitcoin or other Crypto. Products Page... More Info
| CONTACT TEL: 608-238-6001 Email: greg@infinityturbine.com | RSS | AMP |