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Fuel Cell Handbook (Seventh Edition)

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Fuel Cell Handbook (Seventh Edition) ( fuel-cell-handbook-seventh-edition )

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attractive feature of this arrangement is that it eliminates the need for leak-free gas manifolding of the fuel and oxidant streams. However, the seal-less tubular design results in a relatively long current path around the circumference of the cell. For the current YSZ electrolyte to provide sufficient oxygen conductivity, it must be heated to a high temperature (900 to 1,000 °C). This means that expensive, high temperature alloys must be used to house the fuel cell, increasing its cost substantially. These costs could be reduced if the operating temperature was lowered to between 600 to 800 °C, allowing the use of less expensive structural materials such as stainless steel. A lower operating temperature would also ensure a greater overall system efficiency and a reduction in the thermal stress in the ceramic structure, leading to a longer service life for the fuel cell. To lower the operating temperature, either the conductivity of the YSZ must be improved by thinner electrolytes, or alternative electrolytic materials must be developed that can replace YSZ. A concerted effort is being made by researchers around the world to find a better solution. 7.2.1.1 Performance This section provides empirical information that can be used to estimate the performance of SOFCs based on various operating parameters. The SOFCs being developed, particularly the planar types, have unique designs, are constructed of various materials, and are fabricated by different techniques. This development process will result in further evolution of the perfor- mance trends summarized here. The electrochemical reactions associated with hydrogen fuel are expressed in equations (7-4) to (7-6): H2 +O=→H2O+2e- at the anode, and 1⁄2O2 + 2e- → O= at the cathode. The overall cell reaction is H2 + 1⁄2O2 → H2O The corresponding Nernst equation for the reaction in equation 7-6 is RT P P1/2 Ε=Ε°+2Fln H2 O2 PH2O (7-4) (7-5) (7-6) (7-7) In addition to hydrogen, carbon monoxide (CO) and other hydrocarbons such as methane (CH4) can be used as fuels. It is feasible that the water gas shift reaction involving CO (CO + H2O → H2 + CO2) and the steam reforming of CH4 (CH4 + H2O → 3H2 + CO) in the high temperature environment of SOFCs produce H2 that is easily oxidized at the anode. The direct oxidation of CO in fuel cells is also well established. Because of the increased number of chemical species and competing reactions, however, derivation of cell performance as a function of temperature, 7-20

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