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Literature review of Nafion [116]. Researchers [117-120] investigated inorganic material such as silica dioxide (SiO2) and zirconium dioxide (ZrO2) incorporated with the sulfonated polyether-ether ketone (PEEKs) to fabricate inorganic /organic composite membranes for proton exchange membrane fuel cells (PEMFCs) to improve the properties of the membranes in terms of permeability, thermal stability, and rigidity. Composite membranes (such SiO2/SPEEK and ZrO2/ SPEEK) showed a fuel cell potential of 0.6 volt and a power density of 52.9 mW/cm2 which was better than the performance of the Nafion 117 in terms of conductivity [120]. The ionic group (in the membrane) helps the proton transportation across the membrane. The concentration of the ionic group in the membrane needs to be optimized otherwise; the membrane will suffer from the swelling which affects the mechanical properties of the membrane. Therefore, the water uptake (along with the ionic conductivity) of the composite membrane needs to be taken in account when fabricating inorganic /organic composite membranes for fuel cell. Inorganic compounds have the ability to retain water above 100°C in a fuel cell [121]. This can increase the window of the fuel cell operating temperature range which can serve the reaction kinetics at the electrode surface. Staiti et al [121], were able to operate the direct methanol fuel cell (DMFC) at 145°C when using silica/Nafion composite membranes doped with phosphotungstic and silicotungstic acids. The maximum power density of the fuel cell was 400 mW/cm2 by using oxygen feed and 250 mW/cm2 by using air at the cathode. In this case, the high operating temperature (145°C) of fuel cell increased the power density due to three main reasons: Water retention inside the membrane (good proton conductivity) Served the oxidation reaction of methanol at the anode Prevented the poisoning of the platinum catalyst (at the cathode) which caused by the presence of carbon monoxide (CO) 2.4.1 Methods of Preparation of Inorganic/Organic Composite Membrane There are several methods of preparing inorganic with polymer. Depending on the nature of the hybrid materials (inorganic and organic) and the application of the Sirhan AL-Batty Page 63PDF Image | Membrane Electrode Assembly Modification by Zeolite and Graphene Oxide
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