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42 Reactor Reaction Type Feed Operating Conditions Core-Shell Catalyst Xmixed (%) Smixed (%) Ymixed (%) XMR. (%) SMR. (%) YMR. (%) References Direct synthesis of PLMR middle i-paraffins catalytic hydrogen and carbon monoxide 533 K p = 1.0 MPa H2/CO = 2 H-ZSM-5 coated on Co/SiO2 pellets with different size XCO = 93.6 SCH4 = 16.9 XCO = 89.1 SCH4 = 22.4 SCO2 = 6.9 Ci/Cn = 0.74 [234,253,254] Direct synthesis of PLMR i-paraffins catalytic hydrogen and carbon monoxide 533 K p = 1 MPa H2/CO = 2 H-β zeolite coated on Co/Al2O3 catalyst pellets with different size XCO = 80.8 SCH4 = 16.6 SCO2 = 3.9 Ci/Cn = 1.4 XCO = 74.3 SCH4 = 13.6 SCO2 = 2.7 Ci/Cn = 2.3 [239] Direct synthesis of PLMR i-paraffins catalytic hydrogen and carbon monoxide 533 K p = 1 MPa H2/CO = 2 H-ZSM-5 coated on Ru/SiO2 catalyst pellets with different size XCO = 82.1 SCH4 = 17.1 XCO = 81.7 SCH4 = 20.5 SCO2 = 6.1 Ci/Cn = 1.5 [255] Direct synthesis of PLMR i-paraffins catalytic hydrogen and carbon monoxide 533 K p = 1 MPa H2/CO = 2 H-ZSM-5 coated on Pd/SiO2 - XCO = 96.7 XCO = 86.1 SCH4 = 37.4 SCO2 = 7.0 Ci/Cn = 1.88 [256] Direct synthesis of PLMR middle i-paraffins catalytic hydrogen and carbon monoxide 573 K p = 1.0 MPa H2/CO = 1 H-ZSM-5 crystalized on fused-iron catalyst pellet SCH4 = 12.8 SCO2 = 44.7 Ci/Cn = 2.31 XCO = 96.9 SCH4 = 8.7 SCO2 = 33.9 Ci/Cn = 4.17 [257] Synthesis of gasoline-range PLMR hydrogen and carbon monixide 483–533 K p = 2.0 MPa H2/CO = 2 GHSV = 1000 h−1 H-ZSM-5 coated on CoZr catalyst particles XCO = 97.4 SCH4 = 16 S18+ = 5.6 Si-C5-11 = 16.7 XCO = 82.3 SCH4 = 14.8 S18+ = 0.3 Si-C5-11 = 24.7 [258] i-paraffins catalytic Direct synthesis of PLMR hydrogen and carbon monoxide 553 K p = 1 Mpa H2/CO = 2 H-ZSM-5 zeolite coated on Co/SiO2 XCO = 98.5 SCH4 = 23.7 SCO2 = 16 Sn = 53.4 Si = 36.2 XCO = 99.1 SCH4 = 20.1 SCO2 = 18.2 Sn = 47.6 [259] light i-paraffins catalytic Table 2. Cont. SCO2 = 8 Ci/Cn = 0.49 SCO2 = 5 Ci/Cn = 0.42 Si = 43.8PDF Image | Zeolite Catalysis
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