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Chapter 7: Mineral carbonation and industrial uses of carbon dioxide 327 silicate, thus allowing for further digestion of the remaining (Mg(OH)2); however, also in this case the recovery of the NaOH catalyst seems to be very difficult (Blencoe et al., 2003). To overcome the substantial energy penalty of water evaporation in the hydrochloric acid process, it was proposed to dissolve the silicate minerals in a magnesium chloride melt in order either to precipitate Mg(OH)2 as before or to allow for direct carbonation in the melt (Wendt et al., 1998a; 1998b; 1998c; 1998d). No experimental demonstration of this process has been provided, possibly also because of the corrosive conditions of the reaction; energy and material balances indicate that either version of the process will hardly be viable (Newall et al., 2000; Haywood et al., 2001). recovery include acetic acid (Kakizawa et al., 2001), oxalic acid (Park et al., 2003), orthophosphoric acid (Park et al., 2003) and ammonium bisulphate (Pundsack 1967). Among the possible chelating agents that keep either silicates or magnesium ions in solution by forming water-soluble complexes, is EDTA – ethylene-diamine-tetra-acetic acid (Carey et al., 2003; Park et al., 2003; Park and Fan, 2004). Citric acid is also effective because it combines its acidic properties with strong chelating properties (Carey et al., 2003). All these additives have been proven to enhance the dissolution of silicate minerals, but only in the acetic acid case has a complete process scheme, including acid recovery, been described and evaluated (Kakizawa et al., 2001). This is based on two steps, whereby the metal ions are extracted first using acetic acid and then the carbonate is Weaker acids that might reduce the energy requirements for Figure 7.3 Process scheme of the single-step mineral carbonation of olivine in aqueous solution (Courtesy Albany Research Centre). ‘Single-step’ indicates that mineral dissolution and carbonate precipitation take place simultaneously in the same carbonation reactor, whereas more steps are of course needed for the whole process, including preparation of the reactants and separation of the products.PDF Image | CARBON DIOXIDE CAPTURE AND STORAGE
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