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critical point indicated. Assuming a typical coal combustion flue gas with approximately 14% CO2 in light gas, the various lines that are not solid indicate the combination of pressure and temperature at which CO2 fist condenses as either a liquid (dew point) or solid (frost point), and the conditions at which 90%, 95%, and 99% of the CO2 is in the condensed phase. As indicated, higher amounts of capture require increasingly extreme conditions of higher pressure and lower temperature. 10000 1000 100 10 1 0.1 Solid Liquid Vapor Critical Point Triple Point Saturation Line Sublimation Line Melting Line -100-90-80-70-60-50-40-30-20-10 0 10 20 30 40 50 Temperature, °C Figure 5 CO2 phase diagram. The three solid lines separating the solid, liquid, and vapor regions are accurate. The dew/frost point line and the removal lines assume ideal behavior and 14% CO2 in light gas and are conceptually instructive but not quantitatively, and in some cases not even qualitatively, accurate (see following plots). Pressure, barPDF Image | CC Pittsburgh Coal Conference
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