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7 Cp 8 dp 9 dc 10 Dz 11 Dp gas heat capacity, J kg−1 K−1 particle diameter, m column internal diameter, m axial mass dispersion coefficient, m2 s−1 effective intraparticle molar diffusion coefficient, m2 s−1 nanopore-sorbate interaction energy, J mol−1 friction factor, - 12 E 13 f 14 F 15 Fm 16 ∆Ha 17 ∆Hr 18 i species index, - 19 K surface-sorbate interaction parameter, Pa−1 20 kLDF linear driving force intraparticle mass transfer coefficient, s−1 molar flow rate, mol s−1 mass flow rate, mol s−1 adsorption enthalpy, J mol−1 reaction enthalpy water-gas shift, J mol−1 molar mass, kg mol−1 pore-size distribution parameter, - 21 M 22 m 23 n 24 N molar flux, mol m−2 s−1 25 N total number of species, - 26 p pressure,Pa Freundlich isotherm parameter, - 27 pc 28 p0 29 q 30 qeq equilibrium amount adsorbed, mol kg−1 31 qs maximum (monolayer) amount adsorbed, mol kg−1 32 R gas constant, J mol−1 K−1 33 rWGS water-gas shift reaction rate, mol kg−1 s−1 40 u 41 v 42 vm superficial gas velocity, m s−1 interstitial gas velocity, m s−1 molar volume, cm3 mol−1 critical pressure, Pa saturation pressure, extrapolated to T > Tc, Pa excess amount adsorbed, mol kg−1 34 T 35 t 36 te 37 Tc 38 Tw 39 U overall heat transfer coefficient, W m−2 K−1 temperature, K time, s time of complete breakthrough, s critical temperature, K wall temperature, K 2PDF Image | High-temperature pressure swing adsorption cycle design for sorption
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