LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION

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LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION ( limits-small-scale-pressure-swing-adsorption )

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TABLE OF CONTENTS Page ABSTRACT......................................................................................... iv LIST OF TABLES.................................................................................. xi LIST OF FIGURES................................................................................ xiii NOMENCLATURE.............................................................................. xvi CHAPTER I. INTRODUCTION..................................................................... 1 1.1. Purpose........................................................................ 1 1.2. Scope of Work.............................................................. 2 1.3. Intellectual Contributions.................................................. 4 II. BACKGROUND....................................................................... 5 2.1 Zeolites....................................................................... 5 2.1.1 Zeolite History................................................ 6 2.1.2 Zeolite Composition and Structure........................ 7 2.1.3 Zeolite Applications......................................... 11 2.2 Adsorption................................................................ 13 2.2.1 Adsorption Fundamentals.................................. 13 2.2.2 Adsorption Thermodynamics............................. 15 2.2.3 Diffusion in Microporous Adsorbents................... 16 2.3 Air Separation through Pressure Swing Adsorption................ 19 2.3.1 PSA Principles.............................................. 19 2.3.2 History and Growth of PSA............................... 21 2.3.3 Improvements to PSA Cycles............................. 25 vi

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