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repulsive and attractive forces. Figure 2.4 shows potential energy (sum of all the interactions that exist between the adsorbate and adsorbent) as a function of the distance of the adsorbate molecule from the adsorbent surface. The high positive repulsive potential energy near the adsorbent surface is where the electron cloud overlap would occur. The potential well depth, U(r0), is related to the interaction strength between the adsorbate and solid surface. The larger the potential energy difference, the greater the attraction. At zero Kelvin (no kinetic energy), a molecule would settle at the bottom of the well. At all other finite temperatures, the molecule oscillates around the minimum potential energy. Figure 2.4 Potential energy diagram for adsorption7 14PDF Image | LIMITS OF SMALL SCALE PRESSURE SWING ADSORPTION
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