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1 2 Introduction........................................................................................... 1 1.1 Relevance and Motivation .................................................................... 1 1.2 Process System Enterprise ................................................................... 1 1.3 Objectives and Outline ....................................................................... 2 Contextualization and state of art................................................................3 2.1 Pressure Swing Adsorption and its Milestones............................................3 2.2 Adsorption ....................................................................................... 3 2.3 Isotherms ........................................................................................ 4 2.4 Adsorbents ...................................................................................... 5 2.5 PSA basic cycles ................................................................................ 5 2.6 Temperature Swing Adsorption and Vacuum Swing Adsorption ......................6 2.7 Multilayer Adsorption .........................................................................7 2.8 Breakthrough curves .......................................................................... 7 2.9 Pressure Swing Adsorption for Hydrogen Purification .................................. 8 Modelling Tool and Mathematical model ...................................................... 11 3.1 gPROMS® Tool ................................................................................ 11 3.1.1 gPROMS® fundamentals................................................................................ 11 3.1.2 gPROMS® Libraries ...................................................................................... 12 3.2 Component and mathematical model .................................................... 12 3.2.1 Adsorption bed model .................................................................................. 12 3.2.2 Mass balance ............................................................................................. 13 3.2.3 Energy Balance .......................................................................................... 13 3.2.4 Momentum balance ..................................................................................... 14 3.2.5 Linear Driving Force .................................................................................... 14 3.2.6 Fluid properties ......................................................................................... 15 3.2.7 Dispersion model ........................................................................................ 15 3 Pressure Swing Adsorption for Hydrogen Purification Table of contents Notation and glossary ................................................................................... vii iPDF Image | PRESSURE SWING ADSORPTION FOR THE PURIFICATION OF HYDROGEN
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