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Figure Captions Figure 1. Unit cell, including cation sites, for faujasite zeolites Figure 2. The position of extraframework sites in relationship to the sodalite cage in Li- LSX zeolite. Figure 3. The position of extraframework sites in relationship to the sodalite cage in Li,Ag-LSX zeolite. Silver was found in all sites (expect SII') for the Li54.0Ag41.8Na0.2- LSX-450 (i.e., dehydrated at 450oC) sample.o Silver was found in the SII' site only for the Li93.3Ag2.0Na0.7-LSX-350 (dehydrated at 350 C) sample and in the SII' and SII* sites for Li93.3Ag2.0Na0.7-LSX-450 sample. Figure 4. Single component adsorption isotherms, measured at 25 C, for N2, O2, and Ar on Li94.5Na1.5-LSX after vacuum dehydration at 350 C for 4 hours. Figure 5. N2 equilibrium isotherms measured at 25 C. This figure shows the enhancement in the N2 adsorption capacity for Li94.5Na1.5-LSX zeolite over that of Li77.0Na9.0-X zeolite. Both isotherms were measured after vacuum dehydration at 350 C for 4 hours. Figure 6. Single component adsorption isotherms, measured at 25 C, for N2, O2, and Ar on Ag95.7Na0.3-LSX after vacuum dehydration at 450 C for 4 hours. Figure 7. N2 equilibrium isotherms measured at 25 C. This figure shows the enhancement in the N2 adsorption capacity for Ag95.7Na0.3-LSX over that of Ag85.7Na0.3- X. Both isotherms were measured after vacuum dehydration at 350 C for 4 hours. Figure 8. Equilibrium isotherms, measured at 25 C, for adsorption of N2 on various LixAgy-X-1.0 zeolites. The amount adsorbed is given in molec/uc. This shows that the addition of increasing amounts of Ag results in a change in the general aspect of isotherm toward that of the near-fully Ag+-exchanged material. Figure 9. Equilibrium adsorption isotherms, measured at 0 C, 25 C, and 50 C, for N2 adsorption on Li94.2Ag1.1Na0.7-LSX zeolite after vacuum dehydration at 450 C. Figure 10. Plots of ln(P) vs. 1/T at different coverages for Li94.5Na1.5-LSX (top) and Li94.2Ag1.1Na0.7-LSX (bottom). Figure 11. Isosteric heat of adsorption of N2 on Li94.5Na1.5-LSX and Li94.2Ag1.1Na0.7- LSX. 116PDF Image | PSA USING SUPERIOR ADSORBENTS
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