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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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Figure 4.11. Microscopic images of inner surfaces of the PLOT columns at different axial locations. The brown background is the fused silica cover and while clusters are adsorbent particles. .................................................................136 Figure 4.12. Microscopic images of the adsorbent-coated microchannel inner surfaces at different axial locations showing a contiguous adsorbent layer..................138 Figure 4.13. (a) Heat transfer (b) mass transfer test results for sample no. 6 (L = 0.9 m) for a ΔP of 49 kPa.....................................................................................139 Figure 4.14. Adsorption experiment results on customized adsorbent-coated microchannels (a) Adsorption time vs. ΔP (b) average ΔT vs. ΔP (c) average ΔT vs. adsorption time ..............................................................................141 Figure 4.15. SEM images of zeolite 5A adsorbent particles used for fabrication of custom-made adsorbent-coated microchannels..........................................142 Figure 4.16. (a) Heat and (b) mass transfer model validation for sample no. 6 (L = 0.9 m) using adsorbent particle size of 7 μm. (c) heat and (d) mass transfer model validation using adsorbent particle size of 2 μm. The solid lines represent the experimental results, whereas the dashed lines represent the modeling results. .................................................................................................................143 Figure 4.17. Predicted temperature variation with local adsorbent particle diameter varying axially (inlet to outlet) (a) linearly from 2 μm to 7 μm (b) linearly from 7 μm to 2 μm (c) decreasing quadratically from 7 μm at the inlet to 2 μm at the axial midpoint, and then back to 7 μm at the outlet. ...................148 Figure 4.18. Test matrix model validation for adsorbent-coated microchannels for (a) adsorption time (b) ΔT. The dashed lines in ΔT validation represent ΔTMax and the dash-dotted lines represent ΔTmin for the corresponding adsorbent- coated microchannel. ................................................................................150 Figure 4.19. Comparison between predicted and measured values for adsorbent-coated microchannels for (a) Adsorption time (b) ΔT (c) ΔTMax ...........................151 xv

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