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similar approach, new hybrid systems incorporating such superior membrane materials can combine the benefits of membrane separation and adsorption systems. Therefore, along with understanding the separation behavior in MMMs from a membrane standpoint, it is also essential to consider the possibility of incorporating them into adsorption-based systems. Figure 2.1. Improvements in selectivity of mixed matrix membranes by increasing adsorbent loading in polymers (Koros and Mahajan, 2000; Bernardo et al., 2009). Adsorption-based gas separation processes employ preferential adsorption of component gases on solid adsorbent materials, and this phenomenon is controlled by manipulating the pressure (PSA) and temperature (TSA) of the gases under consideration. In a typical PSA process, the adsorbent pellets or crystals are packed to form a porous adsorbent bed through which the mixture components pass. In the adsorption stage of the cycle, the bed is pressurized with the feed mixture, and gas separation takes place by selective adsorption. After the bed is saturated with the adsorbate, it is depressurized, in some cases to near-vacuum pressure (Zhang et al., 2009; Liu et al., 2011), which desorbs 15PDF Image | TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION
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