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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION ( temperature-swing-adsorption-processes-for-gas-separation )

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water in the gas stream affects the adsorption process as shown in Figure 4.20; however, it does not dislodge the adsorbent from the adsorbent layer. Another concern identified in the present work is adsorbent layer manufacturing variability. When a coating and solution drying approach is used for making the adsorbent-coated channels, the layer is discontinuous and non-uniform, giving rise to variable temperature rise during adsorption. Figure 4.11 and Figure 4.12 demonstrate this variability. In large-scale installations, these variations would determine delivered product purities and overall process performance. The predicted adsorption times agree well (4% AAD) with observed adsorption times, and uniformity of the adsorbent layer is critical for accurate predictions of temperature rise. In the presence of a fast-moving liquid with high shear stress, adherence of such a layer to the covering support layer is also an important consideration that must be addressed. Figure 4.20. Drop in adsorption time with test time for repeated baking and because of water adsorption 156

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TEMPERATURE SWING ADSORPTION PROCESSES FOR GAS SEPARATION

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