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Chapter 2 Theory 2.1 Fundamentals of Thermodynamics The behaviour of thermodynamic systems follows the four laws of thermodynamics and the workings of thermodynamic systems may be described in either a macroscopic view, by classical thermody- namic theory, or in a microscopic view, by statistical mechanics theory. The classical view is sufficient for thermodynamic computation of power cycles, however in this theory chapter some statistical descriptions are included for sake of completion and to facilitate the understanding of some key concepts. 2.1.1 Work, Pressure and Heat In thermodynamics the work exerted, or performed, by a system is equal to the energy transferred by the system to its surrounding. Similarly, work can be exerted from the surrounding on the system by the transfer of energy. The pressure-volume work, or simply PV work, occurs when the volume of a system changes due to the pressure exerted on the system boundary. It is also named moving boundary work since it is associating with moving the system boundary. For a closed system the infinitesimal amount of work performed by the system is found as [33] ∂Wb =F ·ds=PA·ds=P ·dV (2.1) 13PDF Image | Analysis of Organic Rankine Cycles for a Boiler Station
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