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Table 4.3 Table of fluid properties and thermal efficiencies Fluid R1233ZD(E) R1234ZE(Z) R245CA R11 R141b R21 SulfurDioxide n-Butane cis-2-Butene EthyleneOxide Chemical form. C3ClF3H2 C3F4H2 C3F5H3 CCl3F C2Cl2F H3 CCl2FH SO2 C4 H10 C4 H8 C2H4O Tcrit [à C] 166.45 150.12 174.42 197.91 204.4 178.3 157.49 152.0 162.6 195.77 Pevap [bar] 22.94 26.897 19.40 16.32702 13.78 25.77 54.890 28.67 26.98 27.35 Pcond [bar] 0.01650 0.01575 0.01587 0.013735 0.01491 0.0144576 0.006619 0.02102 0.009696 0.008035 wexp [kJ/kg] 16.99 16.670 18.70 17.20 21.89 20.16257 27.168 31.47 34.57 50.35 wpump [kJ/kg] 1.605 2.153 1.381 1.038 1.067 1.757 3.7485 4.613 4.0587 3.005 BWR [%] 9.451 12.92 7.385 6.033 4.875 8.714 13.80 14.66 11.74 5.97 ηth [%] 8.390 8.043 8.40 9.067 9.048 8.948 8.71 7.915 8.385 9.314 FoC [%] 30.99 29.70 30.10 33.48 33.41 33.04 32.18 29.23 30.96 34.39 The saturation curves of the fluids investigated are shown in figure 4.7, while water illustrated as a reference. As can be seen in figure 4.7, the critical temperatures of the organic fluids are Figure 4.7: Fluids illustrated in a T-s diagram. substantially lower than the critical temeprature of water. Furthermore, many of them exhibit dry, or isentropic, behaviour during expansion. It can be noted that sulfur dioxide and Ethylene oxide are wet. Furthermore, sulfur dioxide would be promising for ORC application, if it were not extremely toxic and deadly. 60PDF Image | Analysis of Organic Rankine Cycles for a Boiler Station
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