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A∗ + B → AB+ + e (3.7b) 3.1.2.2 Electron and Ion Destruction After this general introduction to the creation of electrons and ions, it is necessary to illustrate the processes by which they may be destroyed. Recombination, attachment, and detachment are the main mechanisms for the loss of charged particles. First electron-ion recombination will be reviewed, followed by ion-ion recombination. Then electron-neutral attachment will be considered, along with the related subject of electron detachment via electron-ion and ion-neutral collisions. Electron-ion recombination can play an important role in plasma-chemical reactions because the recombination is a highly exothermic process [37]. Therefore this excess energy can be transferred to different channels such as molecular dissociation, the release of radiation, or to a third-body partner facilitating the reaction. Dissociative electron-ion recombination is the fastest method for electron destruction in a molecular plasma and follows from the reaction sequence of Equation 3.8 [37]. Here the released energy is used to dissociate the intermediate excited molecule and to excite the atomic product. e+AB+ →(AB)∗ →A+B∗ (3.8) With relatively low plasma densities, radiative electron-ion recombination may occur, though the cross section for this process is not very high. Here the energy is converted to radiation as shown in Equation 3.9 [37]. e+A+ →A∗ →A+ω (3.9) Three-body electron-ion recombination may also occur in atomic gases where the energy is transferred to the third-party electron that participates in the reaction. This 35PDF Image | CO2 Conversion in a Microwave Plasma Catalyst System
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