CO2 Conversion in a Microwave Plasma Catalyst System

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CO2 Conversion in a Microwave Plasma Catalyst System ( co2-conversion-a-microwave-plasma-catalyst-system )

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(a) (b) Figure 6.3: Pictures of plasma with 700 W input power: a) pure Ar discharge, b) Ar plasma with 1% CO2 added. CO and not N2. To circumvent this problem, an initial background RGA scan is taken of the air to determine an initial gas composition. Then Ar flow is injected into the discharge tube and another background scan is recorded for the Ar-dominant environment. In this way, the Ar peak at mass/charge ratio 40 can be corrected for any initial Ar in the air, and the CO peak can be corrected for any nitrogen still remaining in the discharge tube after the injection of Ar. Thus any initial Ar found in the air scan will be subtracted from all subsequent Ar peaks, and any remaining peak at 28 amu/qe existing in the Ar background will be subtracted from all subsequent peaks at 28 amu/qe once CO2 is added. The Ar background will serve to correct for any initial remaining oxygen and CO2 in the system as well. This method provides assurance that any peaks for mass/charge ratios 16, 28, 32, and 44 properly correspond to O, CO, O2, and CO2 created in the plasma system. Figure 6.4 shows an example of an untreated RGA spectrum for air and Ar. The dotted curve representing air shows a dominant peak at 28 for N2 and another peak at 32 for O2. There is also a small peak at 14 which can represent doubly ionized N2 or atomic nitrogen. Once 8 slm of Ar is injected into the discharge tube, 40 becomes 111

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