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Figure 6.12: Effects of Tv on SPECAIR spectrum. Simulated for experimental condition Ar:CO2 = 10:1 at 1 kW with constant Tr = 6050 K and Tel = 13900 K. 6.1.3.2 Plasma Temperatures Through an understanding of how each temperature can affect the computed spectrum, an ideal match for all three temperatures with the experimental spectrum can be found. The results for plasma temperatures generated from SPECAIR simulations are shown in Figure 6.14. The results represent CO2 flow rates from 1-8 slm with 10 slm Ar for power levels 1-2 kW. Given the MS results presented in the previous section, it is assumed that the C2 emission spectra is not influenced by Ar flow rate. Unlike efficiencies, the temperatures seem independent of specific energy as well. The results show thermal non-equilibrium between the electronic temperature and the vibrational and rotational temperatures, Tel >> Tv ≈ Tr. The electronic temperature remains steady around 1.2 eV (14,000 K), which is near the expected value for electron temperature of 1 eV based on the reported results discussed in Section 5.1. However the rotational temperature is in thermal equilibrium with the vibrational temperature 120PDF Image | CO2 Conversion in a Microwave Plasma Catalyst System
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