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Figure 6.13: Effects of Tel on SPECAIR spectrum. Simulated for experimental condition Ar:CO2 = 10:1 at 1 kW with constant Tr = 6050 K and Tv = 7600 K. at 6000 K, significantly higher than the reported values near 300 K (Figure 5.3). The C2 Swan system has been used in several systems to evaluate the temperature of a gas [2,64,75,80]. A similar system using a microwave plasma torch at atmospheric pressure evaluated vibrational and rotational temperatures using the Swan system for CO2 and CO2-N2 plasmas [2]. The results indicated thermal equilibrium between Tr and Tv, with temperatures around 6500 K for the pure CO2 system and around 5500 K for the CO2(97%)-N2(3%) discharge. Another study reported temperature values for a pulsed laser irradiation plasma plume on a graphite target [89]. The resulting C2 emission spectrum indicated rotational temperatures in the range of 5000-6000 K. These temperature values are all in agreement with the experimental temperatures plotted in Figure 6.14 of Tr ≈ 6000 K. However there is still some uncertainty as to whether the C2 system is an adequate indicator of the gas temperature. Emission spectra from the 2nd positive system of N2 (C3Πu - B3Πg) is typically used for gas temperature measurement in air and 121PDF Image | CO2 Conversion in a Microwave Plasma Catalyst System
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