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Supercritical Fluids and Their Application to the Recycling of High-Performance Carbon Fibre Reinforced Composite Materials

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Supercritical Fluids and Their Application to the Recycling of High-Performance Carbon Fibre Reinforced Composite Materials ( supercritical-fluids-and-their-application-recycling-high-pe )

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ability to manipulate the Tg compared to when semi-crystalline samples are used. Therefore, when processing samples at 453 K PEEK undergoes spontaneous thermodynamic crystallisation and is less susceptible to the effects of scCO2 processing. Increasing the processing time above the crystallisation temperature promotes the crystallisation of the polymer and increases the tortuosity for the effusion of CO2. For the plasticisation of the polymer to prevail it is then necessary to increase the processing pressure. In doing so, reductions in Tg of up to 9 K are observed in contrast to reductions of up to 26 K observed when PEEK is processed below Tc. In addition to manipulation of the glass transition temperature, the ability of scCO2 to induce the crystallisation of PEEK below the spontaneous thermodynamic crystallisation temperature was investigated. A cube plot showing the percentage crystallisation observed by DSC with respect to the processing temperature, pressure and time is given in Figure 39. 164

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