Hybrid Fuel Cell Supercritical CO2 Brayton Cycle CO2 Storage

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Hybrid Fuel Cell Supercritical CO2 Brayton Cycle CO2 Storage ( hybrid-fuel-cell-supercritical-co2-brayton-cycle-co2-storage )

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Energies 2020, 13, 5043 11 of 20 4.2. sCO2 Turbine Performance with and without an Integrated FFC Subsystem The computations for the FFCTH assumed that the FFC would achieve similar performance when scaled to design power as it did during the experiment. All thermochemical properties of gases were taken from NIST (Gaithersburg, MD, USA) software MINI-REFPROP [47]. To isolate the effects of integrating the FFC system with the standard sCO2 cycle, the total power generated by the turbine system alone was held constant at 6 MW. To generate this power, Table 4 lists the temperature and pressure of various state points as defined in Figure 1. Table 4. Temperatures and pressures of the state points in the sCO2 cycle. State Point 1 2 2a 3 4 5 5a 6 Temperature (K) 300 318 414 733 913 780 452 331 Pressure (MPa) 7.5 20 20 20 20 7.5 7.5 7.5 The state points in Table 4 were taken from a rate of CO2 required to generate 6 MW of power from the sCO2 turbine system is 4.81 MW. The compression ratio in the system is 2.66. With these parameters, we evaluated the performance of an integrated FFC system, which is able to provide the heat required by sCO2 cycle. Air or oxygen is the oxidant for the FFC system. The oxygen case enables sequestration-ready exhaust from the FFC system. The heat rejected from the pre-cooler (states 6 to 1 in Figure 3) provides heat to separate oxygen from air using a thermally driven adsorption/desorption cycle [38]. If the heat rejected from the sCO2 cycle is not enough to separate enough oxygen for the FFC system, we adjusted the FFC operating voltage to enable more heat rejection. Also note that the efficiency of the air-separation is assumed to be acceptable in the design. The flexibility of the cycle state points to give us this unique opportunity of analyzing this cycle and the assumption is thus justified. The state points will need to be modified depending upon the specific material used for adsorption–desorption pumping of oxygen for air separation [38,39]. The fixed parameters used in the analysis is shown in Table 5. Table 5. Summary of the fixed parameters used in the analysis. Property Power generated by standard supercritical CO2 turbine cycle Efficiency of the standard supercritical CO2 turbine cycle (based on states 1–6) Compression ratio Value 6 MW 53.14% 2.66 previous sCO2 power cycle [40]. The mass flow is 48.35 kg/s. The total amount of heat rejected The fuel flowrate requirement of the FFCTH and its variation with Φ was assessed. The initial conditions for air (or oxygen) entering the fuel-rich combustion chamber of the FFC is 1 bar and 298 K. The Φ of the fuel-rich preburner varies, while Φ of the fuel-lean after-burner remains constant at 0.8. The assumed efficiency for the heat exchangers in the system is 90%. ηfu and ηfc (fixed at 0.7 and 0.5, respectively) are the average experimentally measured results over all Φ. Figure 7 shows the flow rate of methane required to generate the heat (10.8 MW) from the FFC with and without being CO2 sequestration-ready. Figure 7 shows the base-case fuel-flow required to meet the heat requirements with a standard sCO2 turbine cycle (Figure 1).

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