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Working Fluid Selections in Organic Rankine Cycle ICE

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Working Fluid Selections in Organic Rankine Cycle ICE ( working-fluid-selections-organic-rankine-cycle-ice )

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0.18 0.16 0.14 0.12 0.1 0.08 0.06 0.04 0.02 0 R-123 (Original) Water (Original) Benzene (Original) Ethanol (Original) R-123 Ethanol Benzene Water R-245fa R-236ea R-245ca 50 100 150 200 250 300 350 400 Exhaust Gas Temperature (°C) Figure 15. First law efficiency assuming the isentropic efficiencies of the turbine and the pump are 65%. 35000 30000 25000 20000 15000 10000 5000 0 Water (Original) R-123 (Original) Water R-245fa R-123 Benzene Ethanol R-236ea R-245ca 50 100 150 200 250 300 350 400 Exhaust Gas Temperature (°C) Figure 16. Work produced assuming the isentropic efficiencies of the turbine and the pump are 65%. By comparing Figure 15 to Figure 5, I found that the first law efficiencies for refrigerants decrease by roughly 26% (at 150 °C for R-123) of the original efficiency, and for non- refrigerants by about 24% (at 250 °C for water). From Figure 16 and Figure 6, the work for refrigerants drops by about 25% (at 150 °C for R-123) of the original work, and for non- refrigerants by approximately 24% (at 250 °C for water). The drops are expected because we have introduced more irreversibilities into the cycle. The efficiencies of the refrigerants are sensitive to the isentropic efficiencies, but their work is a little less sensitive to the isentropic 23 Work per Unit Exhaust Mass Flow Rate (W/kg) First Law Efficiency ( )

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