Synthetic Polymer-based Membrane for Lithium Ion

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Synthetic Polymer-based Membrane for Lithium Ion ( synthetic-polymer-based-membrane-lithium-ion )

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temperature, the porous structure will be different [74]. Figure 3.4.) depicts the basic steps to use the replica moulding technique. Figure 3.4. The key stages of replica moulding technique. Adapted and reprinted with authorization from [75]. The material composing the mould (micropatterned layer) should not react with the polymer solvent. Additionally, good wettability favors the process as it allows a suitable spread of the prepolymer solution over the pattern layer [76]. In the last years, replica moulding has upsurged as an interesting alternative to fabricating many materials such as poly(dimethylsiloxane) PDMS, hydrogels, thermoplastics, and thermoset composites in desired patterns [77] [78]. 3.5 Freeze extraction In the last decades, a straightforward freeze technique has been widely used to fabricate highly porous and crack-free structures [79, 80]. This method implies the dissolution of a polymer in a solvent with the addition of water. The solution is mixed until an emulsion is 10

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