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Origins, Current Status, and Future Challenges of Green Chemistry

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Origins, Current Status, and Future Challenges of Green Chemistry ( origins-current-status-and-future-challenges-green-chemistry )

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currently in its sixth year, has received nominations from hundreds of companies. The winners of this award exemplify the impressive gains achieved in protecting human health and the environment through the imple- mentation of green chemistry technologies. In June 2001, U.S. President George W. Bush called on “leaders in industry and education to pursue the principles of green chemistry to achieve environmental and economic pros- perity”.100 The green chemistry awards in Italy, Australia, Japan, and the U.K. provide excellent examples of how cutting-edge research and industrial implementation of green chemistry are having a real-world impact. Government Engagement. Multinational engagement, both governmental and nongovernmental, has increased. The Organization for Economic Cooperation and Devel- opment (OECD) launched an initiative in sustainable chemistry in 1998, and the United Nations Industrial Development Organization has more recently focused on green chemistry in conferences in Trieste, Italy, and Buenos Aires, Argentina. IUPAC has been actively engaged through a multidivisional green chemistry initiative as well as through the Chemrawn Committee’s World Conference on Green Chemistry that attracted participation from 31 countries around the world. Future Challenges The future challenges facing green chemistry are as diverse as the scientific imagination and address the broadest issues of sustainability. Because of this breadth, it should be no surprise that a number of these challenges are being pursued for reasons ranging from economic to scientific. Research Challenges. The challenges to research in achieving green chemistry principles are numerous, and a detailed discussion of each is not possible. However, a listing of some of the challenges provides an illustration of current issues and may stimulate thinking on other challenges that should be included: • Transformations utilizing energy rather than material. • Efficient splitting of water by visible light. • Solvent systems that effect efficient heat and mass transfer while catalyzing reactions and intrinsically aiding in product separation. • Development of a synthetic methodologies “toolbox” that is both atom economical and benign to human health and the environment. • Plastics and polymers designed for innocuous deg- radation through the use of additives-free design. • Materials design for recycle/reuse decisions based on embedded entropy. • Development of “preventative toxicology” where increasing knowledge of biological and environmental mechanisms of action are continuously incorporated into the design of chemical products. • Less energy-intensive manufacture of photovoltaic cells that are more efficient. • Development of noncombustion, non-material- intensive energy sources. • Value-added consumptive/fixation uses for CO2 and other greenhouse gases at high volume. • Transformations preserving sensitive functionality without the use of protecting groups. • Development of surfaces and materials that are durable and do not require coatings and cleaners. Implementation Challenges. The discovery of more environmentally benign technologies at the research stage does not guarantee that they will be adopted on an industrial scale. A number of barriers hinder the adoption of newer technologies that prevent pollution. Adoption of environmentally benign processes may be facilitated by the following: • Flexibility in regulations. • Tax incentives for implementing cleaner technologies. • Research programs to facilitate technology transfer among academic institutions, government, and industry. • Patent life extensions for cleaner process optimiza- tion. Education Challenges. Students at all levels can be introduced to the philosophy and practice of green chemistry. Educators need appropriate tools, training, and materials to effectively integrate green chemistry into their teaching and research. Important steps to be taken to advance green chemistry within the curriculum include the following: • Systematic recognition of hazard/toxicity as a physi- cal/chemical property of molecular structure that can be designed and manipulated. • Development and utilization of practical laboratory experiments to illustrate green chemistry principles. • Balanced equations in organic textbooks and replace- ment of “yield” with “atom economy”. • Introduction of the basic concepts of chemical toxicology and the molecular basis of hazard. • Incorporation of green chemistry topics on profes- sional certification exams. • Teacher reference materials for incorporating green chemistry into existing courses. • Education of legislators on the benefits of green chemistry. Conclusion The growth of green chemistry over the course of the past decade needs to increase at an accelerated pace if mo- lecular science is to meet the challenges of sustainability. It has been said that the revolution of one day becomes the new orthodoxy of the next. When the 12 Principles of Green Chemistry are simply incorporated as an integral part of everyday chemistry, there will no longer be a need for the focusing, highlighting, and moniker of green chemistry. And when that day comes, the challenges that chemistry will meet cannot be imagined. Note: Many outstanding examples of green chemistry may be found in the literature. This reference list is not meant to be comprehensive, but includes a representative selection of green chemistry technologies. Origins, Status, and Challenges of Green Chemistry Anastas and Kirchhoff VOL. 35, NO. 9, 2002 / ACCOUNTS OF CHEMICAL RESEARCH 691

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