CARBON DIOXIDE CAPTURE AND STORAGE

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CARBON DIOXIDE CAPTURE AND STORAGE ( carbon-dioxide-capture-and-storage )

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Chapter 5: Underground geological storage 245 years ago (Studlick et al., 1990). Retention times longer than 10 million years are found in many of the world’s petroleum basins (Bradshaw et al., 2005). Therefore evidence from natural systems demonstrates that reservoir seals exist that are able to confine CO2 for millions of years and longer. 5.7.3.2 Engineered systems Evidence from natural gas storage systems enables performance assessments of engineered barriers (wells and associated management and remediation) and of the performance of natural systems that have been altered by pressure cycling (Lippmann and Benson, 2003; Perry, 2005). Approximately 470 natural gas storage facilities are currently operating in the United States with a total storage capacity exceeding 160 Mt natural gas (Figure 5.12). There have been nine documented incidents of significant leakage: five were related to wellbore integrity, each of which was resolved by reworking the wells; three arose from leaks in caprocks, two of which were remediated and one of which led to project abandonment. The final incident involved early project abandonment owing to poor site selection (Perry, 2005). There are no estimates of the total volumes of gas lost resulting from leakage across all the projects. In one recent serious example of leakage, involving wellbore failure at a facility in Kansas, the total mass released was about 3000 t (Lee, 2001), equal to less than 0.002% of the total gas in storage in the United States and Canada. The capacity-weighted median age of the approximately 470 facilities exceeds 25 years. Given that the Kansas failure was among the worst in the cumulative operating history of gas storage facilities, the average annual release rates, expressed as a fraction of stored gas released per year, are likely below 10–5. While such estimates of the expected (or statistical average) release rates are a useful measure of storage effectiveness, they should not be interpreted as implying that release will be a continuous process. The performance of natural gas storage systems may be regarded as a lower bound on that of CO2 storage. One reason for this is that natural gas systems are designed for (and subject to) rapid pressure cycling that increases the probability of caprock leakage. On the other hand, CO2 will dissolve in pore waters (if present), thereby reducing the risk of leakage. Perhaps the only respect in which gas storage systems present lower risks is that CH4 is less corrosive than CO2 to metallic components, such as well casings. Risks are higher in the case of leakage from natural gas storage sites because of the flammable nature of the gas. 5.7.3.3 Fundamental physical, chemical and mechanical processes regarding fate and transport of CO2 in the subsurface As described in Section 5.2, scientific understanding of CO2 storage and in particular performance of storage systems, rests on a large body of knowledge in hydrogeology, petroleum geology, reservoir engineering and related geosciences. Current evaluation has identified a number of processes that alone or in combination can result in very long-term storage. Specifically, the combination of structural and stratigraphic trapping of separate-phase CO2 below low-permeability caprocks, residual CO2 trapping, solubility trapping and mineral trapping can create secure storage over geological time scales. 5.7.3.4 Numerical simulations of long-term storage performance Simulations of CO2 confinement in large-scale storage projects suggest that, neglecting abandoned wells, the movement of Figure 5.27 World oil and gas well distribution and density (courtesy of IHS Energy).

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