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Produced Water from Production of Crude Oil

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Produced Water from Production of Crude Oil ( produced-water-from-production-crude-oil )

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Produced Water White Paper 10 potential concern are salinity, sodicity, and toxicity from various metals. This is discussed further in Chapter 5. 2.2.2.1 Salinity Salinity refers to the amount of total dissolved salts (TDS) in the water and is frequently measured by electrical conductivity (EC), because ions dissolved in water conduct electricity and actual TDS analyses are expensive to conduct. Waters with higher TDS concentrations will be relatively conductive. TDS is measured in parts per million or mg/L and EC is measured in micro-Siemens per centimeter (μS/cm). Irrigation waters that are high in TDS can reduce the availability of water for plant use, diminish the ability of plant roots to incorporate water, and reduce crop yield. Studies have identified the tolerance of various crops to salinity (Horpestad et al. 2001). EC levels of more than 3,000 μS/cm are considered saline (ALL 2003). However, determining salinity threshold values depends on additional factors such as the leaching fraction. Thus, salinity threshold values of 1,000 μS/cm have been calculated for the Tongue and Little Bighorn Rivers and Rosebud Creek, while salinity thresholds of 2,000 μS/cm have been determined for the Powder and Little Powder Rivers and Mizpah Creek (Horpestad et al. 2001). 2.2.2.2 Sodicity Sodicity refers to the amount of sodium in the soil. Irrigation water with excess amounts of sodium can adversely impact soil structure and plant growth. The sodium adsorption ratio (SAR) is the standard measure of sodicity. It is a calculated parameter that relates the concentration of sodium to the sum of the concentrations of calcium and magnesium. The higher the SAR, the greater the potential for reduced permeability, which reduces infiltration, reduces hydraulic conductivity, and causes surface crusting. Irrigation waters with SAR levels greater than 12 are considered sodic (ALL 2003). 2.2.2.3 Other Constituents Also important for determining the suitability of CBM produced water for irrigation are the concentrations of iron, manganese, and boron, which are often found in CBM produced water (ALL 2003). Table 2-2 shows concentration ranges of several constituents in CBM produced waters in the Powder River Basin. Besides crops, CBM produced waters may also affect native riparian and wetlands plants. The SAR thresholds developed to protect irrigation uses, which apply seasonally, may or may not protect the riparian uses, which are continually exposed to water. Because of the lack of data and the site-specific nature of these potential impacts, specific threshold values for protecting riparian plant communities have not been developed. In some cases, CBM may be considered for domestic supplies and drinking water. However, CBM produced waters from coal seams that are greater than 200 feet in depth often have water that exceeds salinity levels appropriate for domestic uses. This level is

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