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Lime Thermal Battery from Infinity Turbine Technology

INFINITY TURBINE LLC We specialize in designs, plans, licensing, consulting, design services, and surplus spare parts. We no longer manufacture turbines or CO2 systems. More Info...

TEL: +1-608-238-6001 (Chicago Time Zone ) USA

Email: greg@infinityturbine.com

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Lime Based Thermal Battery

Your concept describes a lime-based thermal battery—a thermochemical energy storage system using the calcination and hydration cycle of limestone (CaCO₃/CaO/Ca(OH)₂). This is a scientifically valid and potentially highly effective method for storing and releasing heat energy, especially when powered by concentrated solar or surplus electricity.

Cycle Overview: Lime-Based Thermal Battery

Charging Phase (Heat Storage via Calcination):

1. Input: Limestone (CaCO₃), heat from concentrated solar or resistive electric source

2. Reaction (Endothermic):

$$

\text{CaCO₃ (s)} \xrightarrow{\Delta \sim 850–950^\circ C} \text{CaO (s)} + \text{CO₂ (g)}

$$

3. Output: Calcium oxide (CaO) stored as energy-rich material, plus CO₂ (capturable)

This step stores thermal energy in the chemical bonds of CaO.

Discharging Phase (Heat Release via Hydration):

1. Input: Water added to CaO

2. Reaction (Exothermic):

$$

\text{CaO (s)} + \text{H₂O (l)} \rightarrow \text{Ca(OH)₂ (s)} + \text{Heat}

$$

3. Output: Heat (release), hydrated lime (Ca(OH)₂)

This step releases stored heat on demand, ideal for space heating, industrial drying, or steam generation.

Thermochemical Efficiency and Capacity

| Property | Value (Approximate) |

| ------------------------------• | ----------------------------------------• |

| Heat of calcination (input) | \~3.2–3.5 MJ/kg CaCO₃ (\~900–970 kWh/ton) |

| Heat of hydration (output) | \~1.2–1.4 MJ/kg CaO (\~330–390 kWh/ton) |

| Energy density | 250–400 kWh/m³ (solid CaO bulk) |

| Round-trip efficiency | \~35–45% (thermal-to-thermal) |

| Thermal stability | Months to years (CaO is stable dry) |

While not highly efficient like electrochemical batteries, lime thermal batteries excel at large-scale, long-duration heat storage, and have extremely low material cost.

Advantages

| Benefit | Explanation |

| ----------------------------• | ------------------------------------------------------------• |

| Scalable thermal storage | Ideal for megawatt to gigawatt heat banks |

| Abundant, cheap materials | Limestone is plentiful and non-toxic |

| Long shelf-life | CaO can be stored indefinitely if dry |

| CO₂ separability | Can be captured during calcination for reuse or sequestration |

| Modular design | System can be containerized or silo-based |

Challenges and Considerations

| Challenge | Solution/Note |

| ----------------------------• | ------------------------------------------------------------• |

| High charging temperature | Needs CSP or electric heaters >850°C |

| CO₂ handling | Must capture or vent gas safely |

| Hydration control | Hydration is fast and exothermic; must be managed for safety |

| Material degradation | CaO sintering at high temps may reduce reactivity over cycles |

| Round-trip loss | Only partial thermal recovery vs input heat |

Ideal Use Cases

Industrial heat buffering (e.g., drying, calcination, food processing)

District heating

Seasonal thermal energy storage

Renewable heat backup for solar thermal plants

Cement production integration (lime product becomes feedstock)

Conclusion

A lime-based thermal battery is a viable, proven, and scalable thermochemical storage solution, especially suited for concentrated solar thermal systems or electrified industrial heat. It stores energy in the chemical decomposition of limestone and releases it upon hydration—producing substantial heat with zero emissions at the point of use.

CONTACT TEL: +1-608-238-6001 (Chicago Time Zone USA) Email: greg@infinityturbine.com | AMP | PDF